Unblinking Eye
                             The Carbon Transfer Process

 

The Carbon Transfer Process

by Sandy King


History of the Carbon Process

The carbon transfer process is considered by most persons who know it to be one of the most beautiful of all photographic processes. Carbon prints are capable of a wide range of image characteristics, they can be virtually any color or tone, and the final image can  be placed on a wide variety of surfaces, including glass, metal, paper, as well as various kinds of synthetic surfaces. When the final support has a smooth surface carbon prints have a highly unique quality, a discernible relief which gives them a real dimensional quality, especially prominent when the photograph is held sideways to the light. Carbon is without question the most distinctive and stable of all photographic processes, capable of presenting images with a wide range of characteristics, of virtually any color or tone, on a wide variety of surfaces. Finally, carbon transfer prints, which are made up of inert pigment(s) suspended in a hardened gelatin colloid, are the most stable of all photographic prints.

Tonal reproduction is also one of the strong ponts of carbon printing. Carbon has a long tonal scale and excellent straight-line characteristics, qualities which allows the use of fully detailed negatives with long density ranges, resulting in an even and completely linear distribution of tones from the highest lights to the deepest shadows. Compare in the following family of curves a typical carbon curve with typical silver and Pt./Pd. curves.

Figure 1. Family of Curves. Carbon, Pt./Pd. and Silver

The carbon curve has a very linear straight line curve, with little toe or shoulder, and Dmax of over 1.80; the Pt./Pd. curve has a curve with very long toe and shoulder and Dmax of  just less than 1.50; and the silver curve has a short but very pronounced toe and shoulder with Dmax of over 2.0.

The carbon process as practiced today has a long history of use, having been introduced in 1864 by the Englishman Joseph W. Swan. Swan used a paper support, coated on one side with a pigmented-gelatin solution, known as carbon tissue. After sensitization and exposure this tissue was transferred to a temporary support for development. When dry the resulting pigment image was transferred to its final paper support. Swan began marketing carbon materials in 1866, offering his ready-made tissue in three colors, black, sepia and purple-brown.

Carbon was widely practiced in Europe and in the USA throughout the 19th century and well into the 20th. It was considered by many to be the aristocrat of all printing processes, and commercial carbon prints typically cost much more than those produced by any of the other process, including palladium and platinum. The market for carbon materials all but disappeared in the 1950s, although Hanfstaengl of Germany continued to produce small quantities of carbon tissue and transfer papers for monochrome and three-color work until around 1990. Ultrastable, a modern carbon color printing process based on the use of digital negatives and pin registration of the color reliefs, was introduced in the 1990s and enjoyed some popularity as a high-end color printing process, but as of several years ago materials for the process are no longer available.

As of early 2007 the only monochrome carbon tissue available in the US is that manufactured by Bostick and Sullivan in Santa Fe, New Mexico. B&S produces the tissue in several colors, including Forest Green, Nut Brown and Renaissance Black. The tissue is supplied in sheets of 36”X60” at an approximate cost of just under $4.00 per square foot. The tissue is of good quality, with a smooth and uniform coating, and is completely free of bubbles and other surface imperfections.

I strongly encourage anyone interested in experimenting with carbon printing to work first with the B&S carbon tissue before attempting to make your own. However, this article will focus on the home manufacture of carbon tissue and instructions for its use. If you use the B&S tissue be sure to follow the working directions provided by the manufacturer since they are in some ways different from the directions given here for use with home manufactured tissue.


Overview of the Process

Malaspina GalleryCarbon is a contact printing process that gives a final image that comprises a pigment suspended in gelatin placed on a final support, usually paper. To make this image, a negative is placed in contact with a sensitized sheet of carbon tissue and exposed with an ultraviolet light source. This causes the gelatin to harden directly in proportion to negative densities, i.e. the tissue is hardened more in the shadows than in the highlights. After exposure the tissue is soaked briefly in cool water, then squeegeed into contact with a paper or plastic support. After about 30 minutes the tissue on its support is transferred to a tray of water at about 105°F for development. Once the pigmented gelatin has begun to melt the tissue is peeled from the support and discarded. The unhardened gelatin slowly washes away from the support leaving a relief image.

There are two major variations of the monochrome carbon transfer process: single transfer and double transfer. In single transfer the sensitized and exposed tissue is developed directly on its final support. In double transfer the sensitized and exposed tissue is first developed on a temporary support (usually a plastic of the polyester or polyvinyl family), and after drying the image is transferred to a final paper support. The final support is usually paper but may also be glass, metal, or various kinds of synthetic paper supports.

Depending on the final support one should expect some slight increase in density of a carbon print on dry-down, though it is nothing like what we expect with processes like kallitype, pt./pd. or vandyke. And, unlike a pt./pd. print, which loses much of its wet beauty when dry, carbon prints usually have a richer, more brillant look when dry than when wet.

The major steps in making a carbon print are the following.

  1. Make the tissue.
  2. Sensitize and dry the tissue.
  3. Mate a suitable negative with the emulsion side of the tissue and expose with a light source rich in UV.
  4. After exposure, separate the negative from the tissue and soak the latter in water at about 65°F for 45-50 seconds,  and then squeegee the tissue into contact with the final support (single transfer) or with a temporary plastic support (double transfer). Cover the sandwich with a sheet of blotting paper, place a sheet of plate glass over the paper, and leave it undisturbed for about 20-30 minutes.
  5. Transfer the sandwich of tissue/support to a tray of warm water and develop the relief by washing away the insoluble gelatin. This is the final step for single transfer.
  6. For double transfer, allow the image on the temporary plastic support to dry and then transfer it to a final support

We will now describe each of these steps in detail.  Carbon printing is a very flexible process and in every step there are multiple methods that work. However, in this article we must limit discussion to only one or two of the major variations. Consult the sources in the recommend bibliography for more detailed information on the process.


Supplies and Materials: Things You Will Need

What You Will Need

In order to make carbon prints you will need the following chemicals, materials and equipment. Most of the basic ingredients are readily available locally, and inexpensive, a fact that will be much appreciated by those used to the high cost of processes requiring precious metals such as gold, palladium and platinum.

Chemicals and Things

  • Alcohol and/or Acetone
  • Ammonium or potassium dichromate -- Sensitizer
  • Sodium bisulfite or sodium metabisulfite – Clearing Agents
  • Sugar — Plasticizer
  • Glycerine (optional) —  Plasticizer for arid climates.
  • Thymol (optional) — Preservative
  • Pigment — India or Sumi Ink, tube watercolors and numerous othe pure pigments in aqueous dispersion.

Figure 2 – Some of the essential materials needed.

Equipment

  • A few pieces of plate glass, 1/4” thick and two inches larger on all sides that the largest print you intend to make.
  • UV light source
  • Contact Printing Frame or Vacuum Frame
  • Rubber squeegee
  • Plastic trays about two inches larger all around than the largest print you intend to make
  • Drying screens
  • Access to Running Hot and Cold Water
  • Scale for measuring chemicals and gelatin

Materials

  • Carbon Tissue
  • Final Support Paper
  • Thin Mylar sheets


Stage One: Making Carbon Tissue

Bank GalegoIt is recommended that you prepare the pigmented gelatin solution, which I will call henceforth in this article the “glop,”  in one liter quantities. One liter gives a convenient reference point for many existing formulas and provides an adequate amount of solution to make about 10-15 tissues 8X10” in size, or the equivalent. It is not necessary to use all of the glop in one session since it can be frozen and used at a later date, weeks or even months in the future.

  1. Pour 900 ml of distilled water at 65-70°F into a clean wide-mouth container, either glass or plastic. While stirring, add 80 g of gelatin(Bloom 175-250),  to the water and allow the solution to sit for about thirty minutes. Plain Knox gelatin from the grocery store works fine.
  2. Fill a small ice chest, or some other type of insulated container, with warm water at around 115-125°F. Place the gelatin solution (in its container)  in the warm water and allow it to completely liquefy.
  3. When the gelatin solution has completely liquefied, stir in 50g of plain white sugar. The purpose of the sugar is to give pliancy to the dry tissue and prevent it from becoming too brittle. In arid climates the addition of 5-10 ml of glycerine per liter of glop can be added in addition to the sugar to prevent the tissue from drying out too much..
  4. Add the pigment to the gelatin solution, and stir well. Many different kinds of pigment can be used. With some exceptions almost any pigment that disperses well in water can be used. For this formula I am going to recommend either Sumi  or India Ink, or a tube watercolor such as Ivory Black or Lampblack. Both Sumi and Ivory give a warm black color, while India Ink and Lampblack give a very neutral tone black. The exact amount needed depends both on the specific pigment itself and on both how much contrast you want in the tissue (the more pigment you add, the higher the contrast). For your first try, use about 15-20 g of pigment per liter of glop.
  5. Add water to top off the solution to 925 ml and then stir gently for a minute or so. Then add 50 ml of isopropyl alcohol to serve as a surfactant, and 1 ml of a 30% thymol in isopropyl alcohol as a preservative. Finally, top off the solution with distilled water to one liter.
  6. Leave the container of glop in water at about 115-125°F for at least an hour before coating. This should get rid of most of the bubbles stirred up during mixing. .
  7. Coat a suitable base with the glop. Although paper can be used for the tissue base I recommend a plastic such as Denril Multi-Media Vellum or Yupo, a synthetic polypropylene paper. You can coat either by pouring the warm glop directly onto an oversize base and spreading it with your fingers, or by the use of a frame of flexible magnetic sign material over a sheet of galvanized steel plate. Either way, make sure that the room temperature is at about 68-72°F for the duration of the coating.

Simplified Coating Procedure

  1. Level a piece of plate glass, larger by several inches than the largest tissue you plan to coat.
  2. Draw on the tissue base a rectangle with a permanent marker the size of the area you want to coat. The base itself should be at least one to two inches larger on all sides than the coating area. Wet the tissue base, squeegee it to the surface of the plate glass, and blot off with a clean towel.
  3. For coating an area about 8X10” in size, pour about 50 ml  of the warm glop into a small beaker. Gently but rapidly, pour all of the glop onto the center of the base. Then, working very quickly, spread the glop with your fingers over the 8X10” coating area.
  4. The coating will set in 5-10 minutes. When it sets, pick up the tissue and place it on a drying screen, and set it aside to dry. Drying time will range from 3-24 hours, depending on the thickness of the coating, the temperature and humidity of the drying room, and whether or not a fan is used to accelerate drying.

Coating with Magnetic Frames

An alternative to the free hand method of coating described above is the use is of magnetic sign material over a sheet of galvanized steel. With this method you first level a sheet of galvanized steel, squeegee the tissue support to the metal, and place a frame of flexible magnetic sheeting material over the support. The warm glop is poured over the paper, and then evened out either by hand or with a rod. The magnetic sheeting material serves as a dam and keeps the coating solution confined to the area of the frame.

Magnetic sign material is available in a wide range of sizes up to approximately .060”. I use the .040 thick material for most of my own work. Assuming you fill up the frame completely with glop the .040” material will give a wet coating thickness of  approximately 1.0mm. Prepare the sheeting material by cutting out a frame in the material slightly larger the tissue size you wish to make. You can also use strips of magnetic tape, cutting them to form a frame of the desired size and taping the sides together with duct tape.

To coat, first place the galvanized steel plate on a flat surface and level it. Next, place the tissue base briefly in water and then squeegee it to the galvanized steel sheet. Place the magnetic mask over the paper. The magnetic material will stick to the steel through the thickness of the paper with enough force to keep the gelatin from flowing, keeping it entirely confined within the frame. Wipe off excess water with a clean towel.

Pour the pigmented gelatin on the support and rapidly spread it with your hands as evenly as possible over the area of the frame. This can be done very quickly as there is no risk of the glop running out of the coating area as sometimes happens with the free hand method of coating.

Figure 3 – Pouring the glop within the frame of flexible magnetic sheeeting.
(Image courtesy of Mike Robinson)

Figure 4 – Spreding the glop in the frame.
(Image courtesy of Mike Robinson)

It is also possible to even out the coating by rolling a steel tube or threaded rod, preheated to about 125°F, over the glop. First, pour the glop at one end of the frame and quickly spread it over about 2/3 of the surface to be coated. Then, roll the rod or tube, supported by the thickness of the magnetic sheeting material on each side, over the glop from one end of the frame to the other. This action will even out the coating over the base. The rod needs to be long enough to completely cover the cutout of the frame, and it must be rigid enough so that it does not sag in the middle. With practice one should be able to distribute the pigmented gelatin solution evenly with just one passage of the rod. The heat of the rod melts the gelatin as it passes over the glop and dissipates on contact any bubbles that may be on the surface of the pigmented gelatin solution. Done correctly, the surface of the tissue will be as smooth as glass after coating with this method. When the gelatin sets, run a sharp point such as a toothpick or sharp lead pencil around the edges of the mask, lift the tissue and transfer it to a drying screen.

Figure 5 – Spreading the glop with a heated tube.

To determine how much volume of glop is needed in to completely fill the frame and allow some excess, which is necessary with the rod, first convert all of your dimensions to centimeters, then multiply width X length X depth (thickness of the sheeting material). For example, for a tissue 11X14" in size you will need about 100ml of pigmented gelatin solution to achieve a wet coating height of .032". This assumes, of course, that the flexible magnetic sheeting being used for the frame has a thickness of .032”. For sheeting of other thickness just make the above calculations to determine how much coating solution should be used for a given area. Remember, the use of a rod requires that the amount of glop you pour into the frame be slightly in excess of the calculated amount...


Preparing Final Support Papers

Single Transfer Procedure—The final support for single transfer can be either a fixed-out photographic paper or a drawing or watercolor paper that has been sized with a hardened layer of gelatin. Any good quality paper may be used, depending on the final surface desired. I recommend that beginners use fixed out photographic paper for the final support during the learning phase as the sizing of art and drawing papers is a fairly complicated procedure and can lead to much frustration in use if the sizing is not done properly.

Photographic papers are prepared by soaking in a hardening fixer for 5-10 minutes, then washing thoroughly in running water for 15-20 minutes.

Drawing and watercolor papers must be sized with a coating of hardened gelatin. Follow the directions below.

  1. Make up 1000ml of a 3%-5% gelatin solution, following the directions for making carbon tissue.
  2. Soak the drawing or watercolor paper to be sized for 5-10 minutes in warm water, then squeegee it onto a level, flat surface.
  3. Pour about 80-100ml of the 3%-5% gelatin solution into a beaker, add a few drops of a 40% solution of formalin to the solution, pour the solution over the paper and spread evenly using a clean foam brush.

When the gelatin sets, hang the paper to dry. For good results two or more coatings, with drying between each, is usually required.

AlconroquesDouble Transfer Procedure—Papers used for the double transfer procedure should be coated with a relatively soft layer of gelatin that will expand considerably when wetted. This is necessary for complete transfer of the image from the temporary plastic support.  If the gelatin of the paper support is too hard it will not expand sufficiently and certain parts of the image on the plastic, i.e. the highlights, will not come in contact with the gelatin of the final support, resulting in an incomplete transfer. Fixed out photographic papers are not recommended for double transfer since the gelatin of these papers will not normally swell enough to make contact with the image on the temporary plastic support, and this may lead to an incomplete transfer.

Drawing and watercolor papers for double transfer may be prepared as for single transfer with one important difference: in place of formalin or glyoxal use potassium alum as the hardener. Mix two grams of potassium alum dissolved in 100ml of warm water, then add about 5ml of this solution to every 75-100 ml of coating solution. The gelatin of papers hardened with potassium alum will swell much more than that of papers hardened with formalin or glyoxal, thus allowing complete contact with the carbon image on the temporary plastic support.


Sensitizing Carbon Tissue

Either ammonium or potassium dichromate can be used to sensitize the tissue. I use potassium dichromate for tray sensitizing and ammonium dichromate for spirit sensitizing.

The contrast of a carbon image is controlled by matching the dichromate concentration of the sensitizer to the DR (density range) of the negatives: solutions high in dichromate are used for high contrast negatives, solutions low in dichromate for low contrast negatives. Depending on the native contrast of the tissue, and the DR of the negative, the useful strength may range from as low as 1/4% to as high as 4%-6%.  The strength of the sensitizer is expressed as a percent solution, an expression of weight per volume (w/v), indicating how many grams of a chemical are to be dissolved in water to make a final volume of  100ml of solution. For example, to prepare a 3% potassium dichromate sensitizer dissolve 3 grams of potassium dichromate in 90 ml of water  (or 30 grams in 900 ml of water, etc.), then top off to 100 ml or 1000 ml of total solution.

Figure 6 – Tissue spirit sensitized in a 2% ammonium dichromate solution, diluted 1:2 with acetone.

Figure 7. Tissue spirit sensitized with a 4% ammonium dichromate solution, diluted 1:2 with acetone.

Figure 8. Tissue sensitized with a 6% ammonium dichromate solution, diluted 1:2 with acetone.

Carbon tissue can vary greatly in contrast so the exposure scales obtained above with the 2%, 4% and 6% sensitizers would apply only to the specific tissue used for the tests.

In actual practice carbon tissue is sensitized in one of two ways: 1) by soaking the tissue in a tray containing the sensitizer, or; 2) by brushing a solution containing dichromate and a fast drying spirit such as alcohol or acetone directly on the tissue. Tray sensitized tissue takes up to 1-2 hours to dry, while spirit sensitized tissue will dry and be ready for printing within 15-30 minutes. Both methods are capable of giving excellent and repeatable results in monochrome work when used properly. I personally prefer spirit sensitizing because the sensitized tissue dries faster than with tray sensitizing and because it is very efficient in use of materials.

As soon as the tissue is dry a phenomenon known as “dark effect” kicks into gear.  Dark effect is caused by a slow insolubilization of the gelatin of sensitized, unexposed tissue. The practical consequence of the dark effect is a gradual gain in speed, accompanied by a loss of contrast.  The effect is least in a cold, dry environment, and at a maximum in warm, humid conditions. For maximum consistency, maintain the working room at a constant relative humidity of around 50% and always time the exposure of the tissue to within 5-10 minutes of the end of the sensitizing stage.

Tray Sensitizing of Carbon Tissue

Carbon tissue should be sensitized under low-level tungsten illumination or with a yellow bug light. The sensitizing bath should be used at about 55-50°F. and the tissue should be left in the sensitizer for about three minutes. For consistent and repeatable work it is necessary to standardize this operation in terms of solution temperature and time of sensitizing so that the tissue always absorbs the same amount of sensitizer.

If the tissue has dried out excessively it may be necessary to first place it in a tray of cool water for a minute or so and allow it to flatten out before sensitizing. Squeegee to eliminate excess water before transferring the tissue to the sensitizing bath. If the tissue has been stored flat this step can be eliminated.

Place the tissue in the sensitizer and agitate gently for the duration of the three minute sensitizing period.

After three minutes remove the tissue from the sensitizer, allow it to drain for a few seconds, then place it emulsion side down on a clean sheet of acrylic plastic. Squeegee out the sensitizer, remove the tissue from the plastic and hand dry (or dry on a drying screen. Dry the tissue in the dark, or in a room illuminated by a yellow bug light.

The potassium dichromate sensitizer can be reused, but its printing properties change with time and it must either be periodically renewed or replenished.

Figure 9 – Pouring the dichromate sensitizer over the tissue in tray sensitizing.
(Image courtesy of Sam Wang)

Spirit Sensitizing

Spirit sensitized tissue dries much faster than tray sensitized tissue and is also more environmentally friendly since only a very small amount of dichromate solution is needed. Ammonium dichromate is recommended for spirit sensitizing because it can be diluted with either alcohol or acetone and the stock solutions can be mixed at stronger dilutions. Potassium dichromate can also be used, but should only be diluted with acetone. To spirit sensitize a sheet of carbon tissue do the following.

Prepare a dichromate stock solution of 3X the strength necessary. For example, if you need a final strength of 2% prepare a dichromate stock solution of 6%. Then, dilute 1 part of the stock solution of dichromate with 2 parts of the spirit, either acetone or alcohol.

First, place several sheets of newspaper on a cork or foam board. Then, pin the tissue to the board to keep it from moving when brushing.

Figure 10 – Pinning down the tissue in preparation for spirit sensitizing.
(Image courtesy of Sam Wang)

Brush the sensitizer on the tissue using a foam brush. Use a one-inch wide brush for 4X5” and 5X7” tissues, a two-inch wide brush for 8X10” tissue, and a three-inch wide brush for tissue 11X14” and larger.

To coat, first wet the brush in clean water and shake out the excess. Then, pour the required amount of sensitizer directly on the tissue and brush it on: first, brush with parallel strokes on the long dimension; then repeat the process on the short dimension; and finally brush over on the diagonal.

Figure 11 – The author brushing on the spirit sensitizer in subdued light at a workshop in Toronto.
(Image courtesy of Mike Robinson)

Allow the tissue to surface dry and then brush on a second coating. To coat twice you will need approximately 8ml of total solution for an 8X10 tissue, using 4 ml for each coating. Adjust accordingly for other sizes.

After the second coating place the tissue on a drying rack or hang to dry. Drying can be accelerated by directing the air from a fan on the tissue.

Whether the tissue is sensitized in a tray oe with a spirit sensitizer it must be completely dry before it is placed in contact with a negative, otherwise the two could stick together, causing serious damage to the negative.

Continue to Part 2 of The Carbon Transfer Process


 

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